Charge-density-wave partial gap opening in quasi-2D KMo6O17 purple bronze studied by angle resolved photoemission spectroscopy

Low dimensional (LD) metallic oxides have been a subject of continuous interest in the last two decades, mainly due to the electronic instabilities that they present at low temperatures. In particular, charge density waves (CDW) instabilities associated with a strong electron–phonon interaction have been found in Molybdenum metallic oxides such as KMo6O17 purple bronze.We report an angle resolved photoemission (ARPES) study from room temperature (RT) to T 40 K well below the Peierls transition temperature for this material, with CDW transition temperature TCDW 120 K.We have focused on photoemission spectra along GMhigh symmetry direction as well as photoemission measurements were taken as a function of temperature at one representative kF point in the Brillouin zone in order to look for the characteristic gap opening after the phase transition.We found out a pseudogap opening and a decrease in the density of states near the Fermi energy, EF, consistent with the partial removal of the nested portions of the Fermi surface (FS) at temperature below the CDW transition. In order to elucidate possible Fermi liquid (FL) or non- Fermi liquid (NFL) behaviour we have compared the ARPES data with that one reported on quasi-1D K0.3MoO3 blue bronze