Thermal characteristics of manganese (II) nitrate hexahydrate as a phase change material for cooling systems

The imbalance of electrical demand in summer due to cooling system demand is a big problem in many countries. One promising solution is shifting peak demand from early afternoon to night by utilizing natural cold energy resources such as cool outside air during night or running a refrigerator driven by midnight power. In these cases, using the thermal energy storage (TES) of phase change material (PCM) which has a melting point from 15 to 25 °C is one of the most effective ideas. However, few suitable PCMs for this temperature range are at present commercially available. This study aims to evaluate the potential of Mn(NO3)2 • 6H2O (manganese (II) nitrate hexahydrate) as a new PCM for the TES of cooling systems. First, experiments on the modulation of the melting point of Mn(NO3)2 • 6H2O and reduction of supercooling were made by dissolving small amounts of salts in the material. Consequently, MnCl2 • 4H2O was found to have good performance with regard to both modulation of the melting temperature and the heat of fusion. Next, a thermal response test was carried out by using a small cylindrical vessel. Results showed that the required temperature levels for charging and discharging the heat of this mixture were clarified. In addition, the price and safety of this material as a PCM are discussed.