Abstract :
A novel and selective method for the fast determination of trace amounts of Zn(II)ions in
water samples has been developed. The first additional carbonyl and carboxyl functionalized-nano
graphene (SPFNano graphene). The presence of additional carbonyl and carboxyl groups located at the
edge of the sheets makes GO sheets strongly hydrophilic, allowing them to readily swell and disperse in
water. Based on these oxygen functionalities, different model structures of GO were used as absorbent
for extraction of Zn (II) ions by solid phase extraction method. The complexes were eluted with HNO3
(2M)10% V.V-1 methanol in acetone and determined the analyte by flame atomic absorption
spectrometry. The procedure is based on the selective formation of Zn (II) at optimum pH by elution
with organic eluents and determination by flame atomic absorption spectrometry. The method is based
on complex formation on the surface of the ENVI-18 DISKTM disks modified carbonyl and carboxyl
functionalized-nano graphene oxide molecules covalently bonded together followed by stripping of the
retained species by minimum amounts of appropriate organic solvents. The elution is efficient and
quantitative. The effect of potential interfering ions, pH, SPFNano graphene, amount, stripping solvent,
and sample flow rate were also investigated. Under the optimal experimental conditions, the breakthrough
volume was found to about 1000mL providing a preconcentration factor of 500. The maximum
capacity of the disks was found to be 456± 3 ?g for Zn2+.The limit of detection of the proposed method
is 5ng per 1000mL.The method was applied to the extraction and recovery of Zn in different water
samples.
