The development of compression damage zones in fibrous composites

Recent experimental work (Narayanan S, Schadler LS. Mechanisms of kink band formation in graphite/epoxy compsites: a micromechanical experimental study. Comp Sci Technol 1999; 59:2201-13) suggests that kink bands in unidirectional continuous carbon fiber reinforced polymer composites initiate from damage zones formed under axial compressive loads. A damage zone consists of a cluster of locally crushed fibers and broken fibers, that are often fractured at an angle, θ > 0°, normal to the fiber axis. Typically, under compressive loads, fiber breaks in damage zones form roughly along a plane at an angle φ, normal to the fiber axis. These damage zones produce stress concentrations which can lead to instabilities in the nearby fiber and matrix and initiate microbuckling and kink bands. This paper extends a micromechanical influence function technique based on earlier shear lag fiber composite models. Our modified technique calculates the fiber axial and matrix shear stress concentrations due to multiple angled and crushed fibers in arbitrary configurations. Modeling reveals that angled or ‘shear’ breaks (θ > 0°) can lead to higher shear stress concentrations in the matrix than transverse breaks (θ=0°). Also we find that the damage zone is more likely to form at an angle φ, which is greater than that of its individual fiber breaks, θ. When φ is slightly greater than θ, the shear stress in the surrounding matrix regions within the damage zone achieves a maximum, potentially weakening the matrix and interface and consequently leading to kink band formation. Monte Carlo simulations incorporating this stress analysis predict that the initiation and propagation of crushed and angled breaks progress roughly along an angle, φ ≈ 17° in a linear elastic system. When possible, our model results are compared to strain measurements of fiber composites under compression obtained by Narayanan and Schadler using micro-Raman spectroscopy (MRS).