Title of article :
Reinforcing potential of micro- and nano-sized fibers in the starch-based biocomposites
Author/Authors :
Nattakan Soykeabkaew، نويسنده , , Nittaya Laosat، نويسنده , , Atitaya Ngaokla، نويسنده , , Natthawut Yodsuwan، نويسنده , , Tawee Tunkasiri، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Pages :
8
From page :
845
To page :
852
Abstract :
Starch-based biocomposites reinforced with jute (micro-sized fiber) and bacterial cellulose (BC) (nano-sized fiber) were prepared by film casting. Reinforcement in the composites is essentially influenced by fiber nature, and amount of loading. The optimum amount of fiber loading for jute and bacterial cellulose in each composite system are 60 wt% and 50 wt% (of starch weight), respectively. Mechanical properties are largely improved due to the strong hydrogen interaction between the starch matrix and cellulose fiber together with good fiber dispersion and impregnation in these composites revealed by SEM. The composites reinforced with 40 wt% or higher bacterial cellulose contents have markedly superior mechanical properties than those reinforced with jute. Young’s modulus and tensile strength of the optimum 50 wt% bacterial cellulose reinforced composite averaged 2.6 GPa and 58 MPa, respectively. These values are 106-fold and 20-fold more than the pure starch/glycerol film. DMTA revealed that the presence of bacterial cellulose (with optimum loading) significantly enhanced the storage modulus and glass transition temperature of the composite, with a 35 °C increment. Thermal degradation of the bacterial cellulose component occurred at higher temperatures implying improved thermal stability. The composites reinforced with bacterial cellulose also had much better water resistance than those associated with jute. In addition, even at high fiber loading, the composites reinforced by bacterial cellulose clearly retain an exceptional level of optical transparency owing to the effect of the nano-sized fibers and also good interfacial bonding between the matrix and bacterial cellulose.
Keywords :
B. Mechanical properties , A. Nano composites , B. Thermal properties , D. Dynamic mechanical thermal analysis (DMTA) , D. Scanning electron microscopy (SEM)
Journal title :
COMPOSITES SCIENCE AND TECHNOLOGY
Serial Year :
2012
Journal title :
COMPOSITES SCIENCE AND TECHNOLOGY
Record number :
1043985
Link To Document :
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