MgO-templated porous carbons-based CO2 adsorbents produced by KOH activation

Nanoporous (styrene–divinylbenzene)-based ion exchange resin-based carbons (MPCs) were prepared by MgO-templating synthesis and activated by KOH. MPCs were prepared from a (styrene–divinylbenzene)-based ion exchange resin by the carbonization of a mixture with Mg gluconate at 900 °C. And then, the prepared MPCs were treated with KOH at KOH/MPCs ratios ranging from 0.5 to 4 at 800 °C. Low KOH/MPCs ratios (KOH/MPCs ratio = 1) tended to favor the formation of micropores, whereas higher KOH/MPCs (KOH/MPCs ratio = 4) led to the formation of mesopores. The treated MPCs with a KOH/MPCs ratio = 1 exhibited the best CO2 adsorption value of 266 mg g−1 at 1 bar. However, the treated MPCs with a KOH/MPCs ratio = 3 exhibited the best CO2 adsorption value of 1385 mg g−1 at 30 bar. This result indicated that the CO2 adsorption capacity of nanoporous carbons attributed to the mesopore volume fraction at higher pressure.