Electrical properties of a novel lead alkoxide precursor: Lead glycolate

The reaction of lead acetate trihydrate Pb(CH3COO)2·3H2O and ethylene glycol, using triethylenetetramine (TETA) as a catalyst, provides in one step access to a polymer-like precursor of lead glycolate [single bondPbOCH2CH2Osingle bond]. On the basis of high-resolution mass spectroscopy, chemical analysis composition, FTIR, 13C-solid state NMR and TGA, the lead glycolate precursor can be identified as a trimer structure. The FTIR spectrum demonstrates the characteristics of lead glycolate; the peaks at 1086 and 1042 cm−1 can be assigned to the Csingle bondOsingle bondPb stretchings. The 13C-solid state NMR spectrum gives notably only one peak at 68.639 ppm belonging to the ethylene glycol ligand. The phase transformations of lead glycolate and lead acetate trihydrate to lead oxide, their microstructures, and electrical properties were found to vary with increasing temperature. The lead glycolate precursor has superior electrical properties relative to those of lead acetate trihydrate, suggesting that the lead glycolate precursor can possibly be used as a starting material for producing electrical and semiconducting ceramics, viz. ferroelectric, anti-ferroelectric, and piezoelectric materials.