Author/Authors :
Wonjoo Lee a، نويسنده , , Chang Gon Kwak، نويسنده , , R.S. Mane a، نويسنده , , SUN-KI MIN، نويسنده , , Gangri Cai، نويسنده , , T. Ganesh، نويسنده , , Gumae Koo، نويسنده , , James Jinho Chang، نويسنده , , Byung Won Cho، نويسنده , , Sei-Ki Kim، نويسنده , , Sung-Hwan Han، نويسنده ,
Abstract :
A Ru(2,2′-bipyridine-4,4′-dicarboxylic acid)2(NCS)2 [RuL2(NCS)2]/di-(3-aminopropyl)-viologen (DAPV)/tin oxide (SnO2) system was prepared and applied to extensive photocurrent generation with its maximum surface area. The SnO2 thin films on tin-doped indium oxide (ITO) were prepared using the chemical bath deposition method. Then, RuL2(NCS)2/DAPV on SnO2/ITO was easily prepared using self-assembled monolayers (SAMs). The photocurrent measurement of the system showed an excellent photocurrent of 20 nA cm−2 under the air mass 1.5 conditions (100 mW cm−2), which was increased by a factor of four compared to ones without SnO2 layers.
Keywords :
Photocurrent , Surface modification , Chemical bath deposition , SnO2 , Self-assembled monolayers