Rapid synthesis of graphitic carbon nitride powders by metathesis reaction between CaCN2 and C2Cl6

Carbon nitride powders were rapidly synthesized at low temperature via the chemical metathesis reaction between CaCN2 and C2Cl6. X-ray diffraction results confirm the formation of crystalline graphitic carbon nitride. Besides the dominant morphology of nanoparticles, flakes, nanorods, hollow and solid spheres can be observed by transmission electron microscopy. The absorption peaks of Csingle bondN, Cdouble bond; length as m-dashN and s-triazine rings, as well as the absence of Ctriple bond; length of mdashN peak in the infrared spectra, further verify the formation of graphite-like sp2-bonded structure with planar networks. Elemental analysis gives an atomic ratio of N/C around 0.3. X-ray photoelectron spectra exhibit the existence of chemical bonding between C and N.