Title of article :
Pd(II)Cl2 Mediated Oxidative Cyclisation of Hydroxy-Vinylfurans to Lactols: Synthesis of Hagenʹs Gland Lactones
Author/Authors :
Hari Babu Mereyala، نويسنده , , Rajendrakumar Reddy Gadikota، نويسنده , , K.Sugnana Sunder، نويسنده , , S Shailaja، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
A concise synthesis of Hagenʹs gland lactones 3–6 by a chiron approach starting from d-mannose is described. Transformation of d-mannose to dihydroxy-vinylfuran 8 followed by Pd(II)Cl2 mediated oxidative cyclisation to obtain the tetrahydrofurofuran diol 7 constituted the key reaction in the total synthesis of 3–6.
Keywords :
Furans , Lactones , Cyclisation , Pd and related compounds
Journal title :
Tetrahedron
Journal title :
Tetrahedron
