• Title of article

    Π-Face Diastereoselection: Stereochemistry and Reactivity of Addition Reactions on Conformationally Rigid Substrates: 5-X-Adamantan-2-ones and trans-10-X-Decal-2-ones

  • Author/Authors

    Giorgio Di Maio، نويسنده , , Gianfranco Solito، نويسنده , , Maria Rosaria Var??، نويسنده , , Elisabetta Vecchi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    7
  • From page
    7237
  • To page
    7243
  • Abstract
    Stereochemistry and relative rates kax and keq of addition reactions on title compounds have been measured under eight different reaction conditions (MeMgI in Et2O and C6H6, MeMgCl in THF, MeLi at 20 and −78°C, Me2Zn in Et2O, Me3Al in the ratio 1:1 reactant:substrate in toluene and Me2CuLi/MeLi in Et2O at −78°C). Our kinetic data do not fit with current theories of π-face diastereoselection.
  • Keywords
    addition reactions , kinetics , 5-X-adamantan-2-ones , ?-face diastereoselection
  • Journal title
    Tetrahedron
  • Serial Year
    2000
  • Journal title
    Tetrahedron
  • Record number

    1081223

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1081223