Title of article :
Regioselective Synthesis of β- and γ-Thujaplicins
Author/Authors :
Min Gyu Soung، نويسنده , , Masanao Matsui، نويسنده , , Takeshi Kitahara، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
β-Thujaplicin (hinokitiol) 1 and γ-thujaplicin 2, as the first naturally occurring monocyclic tropolone, were regioselectively synthesized from (R)-(+)-limonene, by using different dienyl silyl ether intermediates, 7 and 10, in 18% overall yield via 11 steps and 22% overall yield via 10 steps, respectively.
Keywords :
?-thujaplicin (hinokitiol) , ?-thujaplicin , thermodynamic dienyl silyl ether , Limonene
Journal title :
Tetrahedron
Journal title :
Tetrahedron