Title of article
Regioselective Reductive Heck Arylation of a Rigid Tetracyclic Oxanorbornene Scaffold
Author/Authors
Andreas W?llberg، نويسنده , , Goran Magnusson، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8533
To page
8537
Abstract
Reductive Heck arylation of the tetracyclic oxanorbornene (1) was found to proceed with complete regioselectivity. A number of aryl iodides were investigated, all giving the same selectivity. Modifications within the scaffold were also tested, giving a 84:16 ratio of regioisomers in the worst case. The regioselectivity is probably due to steric factors.
Keywords
Heck reactions , arylation , conformationally rigid compounds , Regioselective
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081366
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