Title of article
Asymmetric hetero-Diels–Alder reaction of chiral pinanediol 1,3-dienylboronates with azo-compounds
Author/Authors
Ao Zhang، نويسنده , , Ying Kan، نويسنده , , Biao Jiang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
5
From page
2305
To page
2309
Abstract
The asymmetric hetero-Diels–Alder reaction of 1,3-dienylboronates 1a and 1b with azo-compounds was investigated. The inductive effect of the methyl in 1,3-dienylboronate 1a resulted in an unusual product 7, while the normal cycloadduct 8 could be obtained as the single stereoisomer by using 1,3-dienylboronate 1b.
Keywords
Diels–Alder reaction , vinylboronic ester , azo-compounds
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1081807
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