Title of article
A novel reaction of ninhydrin with chlorotrialkylsilane leading to ninhydrin dimers, and their X-ray structural analysis
Author/Authors
Masami Sakamoto، نويسنده , , Manabu Watanabe، نويسنده , , Takashi Mino، نويسنده , , Tsutomu Fujita، نويسنده , , Hikoto Ohta، نويسنده , , Shinichi Suzuki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
4687
To page
4689
Abstract
The reaction of ninhydrin with chlorotrialkylsilane gave a silylated ninhydrin dimer accompanied with bis(trialkylsilyloxy) derivatives; the dimeric structure was established by X-ray crystallographic analysis. The dimer is soluble in a nonpolar solvent and easily reproduces ninhydrin under mild conditions; thus it can be used as an equivalent molecule of ninhydrin for utilization as a detecting reagent.
Keywords
Ninhydrin , chlorotrialkylsilane , detecting reagent , ketal , dimer
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082056
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