Author/Authors :
S Caddick، نويسنده , , S Cheung، نويسنده , , V.E Doyle، نويسنده , , L.M Frost، نويسنده , , M.G Soscia، نويسنده , , V.M Delisser، نويسنده , , M.R.V Williams، نويسنده , , Z.C Etheridge، نويسنده , , S Khan، نويسنده , , P.B Hitchcock، نويسنده , , Garry Pairaudeau، نويسنده , , S Vile، نويسنده ,
Abstract :
Dihydroxylated cyclopentenones can be readily synthesised via a base mediated isomerisation reaction. These species and their derivatives can be used to provide a wide range of synthetically useful intermediates by participation in a variety of stereoselective transformations. These include: nucleophilic and conjugate addition, intermolecular cycloaddition, intramolecular free-radical cyclisation and palladium mediated coupling reactions.
Keywords :
Cyclopentenones , Coupling reactions , Diels–Alder reactions , radical cyclisations , Grignard reactions , Conjugate addition
