Title of article
Chiral 2-(2-diphenylphosphinophenyl)-5,6,7,8-tetrahydroquinolines: new P–N ligands for asymmetric catalysis
Author/Authors
Giorgio Chelucci، نويسنده , , Antonio Saba، نويسنده , , Franco Soccolini، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
8
From page
9989
To page
9996
Abstract
New chiral phosphorus–nitrogen ligands, specifically, 2-(2-diphenylphosphinophenyl)-5,6,7,8-tetrahydroquinolines were prepared and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate. Enantioselectivity up to 71% was obtained.
Keywords
enantioselective allylic substitution reactions , phosphinopyridine ligands , palladium catalysts
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082621
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