Title of article
Cleavage of the oxygen bridge in 8-oxabicyclo[3.2.1]octanes by reductive elimination
Author/Authors
Baldur F?hlisch، نويسنده , , Günter Kreiselmeier، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
12
From page
10077
To page
10088
Abstract
Several 2(4)-bromo- or chloro-8-oxabicyclo[3.2.1]oct-6-en-3-ones (2), available by [4+3] cycloaddition of monohalogeno-oxyallyl intermediates with furans, were reduced to halogenated 8-oxabicyclo[3.2.1]oct-6-en-3endo-ols (6) and saturated analogues (7). Cycloheptene-1,3trans-diols (8,11) were formed preferentially by reductive elimination.
Keywords
haloketones , cycloheptenes , oxyallyl intermediates , Halohydrins , Diols , Furans , Cycloadditions
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1082632
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