Title of article
Regio- and stereoselective synthesis of chiral (αS)-(Z)-trifluoromethyl-β-aryl-enamines
Author/Authors
Biao Jiang، نويسنده , , Fangjiang Zhang، نويسنده , , Wennan Xiong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
261
To page
264
Abstract
Chiral (αS)-(Z)-trifluoromethyl-β-aryl-enamines were regio and stereoselectiveally prepared in excellent yields by the one pot reaction of 2-aryl-1-chloro-1-trifluoromethylethlene with lithium (αS)-(α-methylbenzyl) benzylamide. A mechanism involving elimination and addition processes is discussed.
Keywords
trifluoromethyl enamines , stereoselection , lithium amide , Michael addition
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1082704
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