Title of article :
Making molecular-necklaces from rotaxanes
Author/Authors :
Sheng-Hsien Chiu، نويسنده , , Stuart J Rowan، نويسنده , , Stuart J. Cantrill، نويسنده , , Ludek Ridvan، نويسنده , , Peter R Ashton، نويسنده , , Robin L Garrell، نويسنده , , J Fraser Stoddart، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
During an attempt to synthesize polyrotaxanes by Wittig step-growth polymerization between a dibenzylic bis(triphenylphosphonium)-stoppered [2]rotaxane, with an NH2+ recognition site encircled by a DB24C8 ring, and appropriate derivatives of terephthaldehyde carrying bulky groups, large macrocyclic compounds with the topologies of catenanes and molecular-necklaces, are formed.
Keywords :
molecular-necklaces , molecular recognition , Rotaxanes , Self-assembly , Wittig reaction
Journal title :
Tetrahedron
Journal title :
Tetrahedron