Title of article
Synthesis of the proton-ionizable lariat crown ether and chiral recognition of primary amines
Author/Authors
Kazunori Tsubaki، نويسنده , , Masafumi Zeze and Hiroyuki Tanaka، نويسنده , , Takayoshi Kinoshita، نويسنده , , Kaoru Fuji، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
6
From page
1679
To page
1684
Abstract
An optically active proton-ionizable lariat crown ether derivative was prepared. Host displays enantiomeric selectivity toward phenylglycinol (Klarge/Ksmall=3.2) and phenylalaninol (Klarge/Ksmall=1.7). The key intermediate was synthesized in two steps from commercially available binaphthol in 30% yield.
Keywords
amino alcohol , Crown ether , 1 , 1?-binaphthyl , Chiral recognition
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1082848
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