Title of article :
Are there concentration effects in enantioselective deprotonation of cyclic ketones?
Author/Authors :
Marek Majewski، نويسنده , , Fan Wang، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
5
From page :
4567
To page :
4571
Abstract :
Deprotonation of tropinone and its sulfur analog (8-thiabicyclo[3.2.1]octan-3-one, TBON) with chiral lithium amides (e.g. lithium N-benzyl-α-methylbenzylamide), followed by addition of the resulting enolates to benzaldehyde, affords non-racemic products, the enantiomeric excess of which depends on the concentration of the lithium amide.
Keywords :
quinines , Phenols , Epoxidation , aryl O-t-butyl carbonate deprotection , neutral sphingomyelinase , Dihydroxylation
Journal title :
Tetrahedron
Serial Year :
2002
Journal title :
Tetrahedron
Record number :
1083148
Link To Document :
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