Title of article
Synthesis of ferrocenylglucose phosphonite and bisphosphinite: Pd(II) and Pt(II) complexes, Pd-catalyzed allylic alkylation
Author/Authors
Alexey A Nazarov، نويسنده , , Christian G Hartinger، نويسنده , , Vladimir B Arion، نويسنده , , Gerald Giester، نويسنده , , Bernhard K. Keppler، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
8489
To page
8492
Abstract
The synthesis and characterization of the new phosphorus containing ligands and the corresponding Pd(II) and Pt(II) complexes are reported. The molecular structure of 4,6-bis-O-(diphenylphosphino)-2,3-(ferrocene-1,1′-dicarbonyl)-O-methyl-α-d-glucopyranoside was determined by X-ray diffraction methods. The new ligands show good activity (90%) and moderate stereoselectivity (39% ee) in the Pd-catalyzed enantioselective allylic alkylation.
Keywords
phosphonite , Ferrocene , phosphinite , Catalysis , coordination compound , Palladium , Platinum , Enantioselective
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083560
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