Title of article
Salt effect on the endo/exo ratio of the reaction of cyclopentadiene with methyl methacrylate
Author/Authors
Suvarna S. Deshpande، نويسنده , , Usha D. Phalgune، نويسنده , , Anil Kumar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
8759
To page
8762
Abstract
The salt effect on the stereoselectivity of the reaction of cyclopentadiene with methyl methacrylate has been investigated. CaCl2, Na2SO4, KCl and LiCl enhance the endo/exo ratios, while guanidinium chloride (GnCl) and LiClO4 decrease them. The results are supported by independent calculations of salting-out and in coefficients.
Keywords
Salting-out , Diels–Alder reaction , salt solution
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083589
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