Title of article :
Palladium-catalyzed hydrophenylation of bicyclic alkenes
Author/Authors :
Peter Mayo، نويسنده , , William Tam، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Palladium-catalyzed hydrophenylation reactions of bicyclic alkenes were investigated. These reactions were found to be completely chemo- and stereoselective, giving only exo products on the less substituted double bonds of bicyclic alkenes in moderate to good yields. For unsymmetrical bicyclic alkenes, regioselectivities of 52:48 to 100:0 were observed with various substituents on the bicyclic alkenes.
Keywords :
Palladium , bicyclic alkenes , Stereoselectivity , Chemoselectivity , Regioselectivity , hydrophenylation , Heck coupling
Journal title :
Tetrahedron
Journal title :
Tetrahedron
