Title of article
Stereoselective synthesis of (S)-(+)-lycoperdic acid through an endo selective hydroxylation of the chiral bicyclic lactam enolate with MoOPH
Author/Authors
Kazuishi Makino، نويسنده , , Kensuke Shintani، نويسنده , , Takahiro Yamatake، نويسنده , , Osamu Hara، نويسنده , , Keiichiro Hatano، نويسنده , , Yasumasa Hamada، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
9737
To page
9740
Abstract
Efficient synthesis of (S)-(+)-lycoperdic acid has been achieved by use of the stereoselective hydroxylation of the enolate derived from the bicyclic lactam with the molybdenum oxidizing reagent, MoOPH (MoO5·Py·HMPA, oxodiperoxymolybdenum(pyridine)(hexamethylphosphoric triamide)), as a key step.
Keywords
(S)-(+)-lycoperdic acid , Hydroxylation , endo selectivity , MoOPH , bicyclic lactam
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083685
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