Title of article
Double thioalkylation/arylation of nitroarenes with the reduction of nitro- to amino group
Author/Authors
Zbigniew Wr?bel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
10
From page
101
To page
110
Abstract
Some active bicyclic nitroarenes readily react with an excess of alkyl/arylthiols in the presence of DBU and bis-trimethylsilylacetamide (BSA) in DMF solution, to give dithioalkyl/aryl substituted anilines in moderate to good yields via displacement of ortho- and para-hydrogen atoms with simultaneous reduction of the nitro- to amino-group.
Keywords
Amines , Reduction , bicyclic aromatic compounds , Thiols , Substitution
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1083782
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