• Title of article

    Synthesis of hydroquinone-, biphenol-, and binaphthol-containing aza macroheterocycles via regioselective hydroformylation and reductive amination

  • Author/Authors

    Goran Angelovski، نويسنده , , Peter Eilbracht، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    10
  • From page
    8265
  • To page
    8274
  • Abstract
    Rhodium(I) catalyzed regioselective hydroformylation of diolefins and subsequent reductive amination of the dialdehydes in the presence of α,ω-diamines is applied to azamacroheterocyclic ring synthesis. Starting from aromatic diallyl ethers of hydroquinone, biphenol and binaphthol 20–28 membered macroheterocycles were obtained in up to 78% yield.
  • Keywords
    rhodium catalysis , chiral ligands , BINOL , Macrocycles , hydroaminomethylation , regioselective hydroformylation , Reductive amination
  • Journal title
    Tetrahedron
  • Serial Year
    2003
  • Journal title
    Tetrahedron
  • Record number

    1084382

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1084382