Title of article
Free-radical functionalisation of vinylcyclopropanes
Author/Authors
Olivier Andrey، نويسنده , , Boris Camuzat-Dedenis، نويسنده , , Laurent Chabaud، نويسنده , , Karine Julienne، نويسنده , , Yannick Landais، نويسنده , , Liliana Parra-Rapado، نويسنده , , Philippe Renaud، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
8
From page
8543
To page
8550
Abstract
Free-radical mediated cyclopropane ring opening of 2-silylbicyclo[3.1.0]hexane has been carried out leading to the corresponding trisubstituted cyclopentenes and in good yield with complete 1,2-stereocontrol. [3+2]-Annulation has also been performed by trapping the resulting radical with electron-rich and electron-poor olefins, leading to the corresponding polycyclic compounds. Further studies on the functionalisation of dihydropyridines and pyrroles using this methodology is also described.
Keywords
Radicals , silicon and compounds , Cyclopropanes , selenium and compounds , annulation , allylsilanes
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084408
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