Title of article
Stereoselective migration of sterically hindered organoboranes in cyclic and acyclic systems. A stereoselective allylic C–H activation reaction
Author/Authors
Eike Hupe، نويسنده , , Dmitri Denisenko، نويسنده , , Paul Knochel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
12
From page
9187
To page
9198
Abstract
The thermal migration of cyclic and acyclic organoboranes were studied. In most cases, a stereoselective 1,2-dyotropic migration was observed, allowing the stereocontrol of three contiguous chiral centers. Scope and limitations of this thermal migration are presented.
Keywords
Stereoselective synthesis , 1 , Organoboranes , Amination , C–H-activation , 2-Migration
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084469
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