Title of article :
Lithiation of optically active oxazolinyloxiranes: configurational stability
Author/Authors :
Renzo Luisi، نويسنده , , Vito Capriati، نويسنده , , Claudia Carlucci، نويسنده , , Leonardo Degennaro، نويسنده , , Saverio Florio، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
The α-lithiation reaction of optically active oxazolinyloxiranes has been investigated. The trapping reaction with D2O, MeI and acetone affording substituted oxazolinyloxiranes proved that the corresponding lithiated species are configurationally unstable. A stereoconvergency was observed in the case of lithiation–deuteration sequence of two oxazolinyloxiranes.
Keywords :
Oxazolines , lithiation , Stereochemistry , Configuration , oxiranes
Journal title :
Tetrahedron
Journal title :
Tetrahedron
