Title of article
A convergent total synthesis of epolactaene: an application of the bridgehead oxiranyl anion strategy
Author/Authors
Kouji Kuramochi، نويسنده , , Seigo Nagata، نويسنده , , Hideyoshi Itaya، نويسنده , , Yasuaki Matsubara، نويسنده , , Takashi Sunoki، نويسنده , , Hiromi Uchiro، نويسنده , , Ken-ichi Takao، نويسنده , , Susumu Kobayashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
16
From page
9743
To page
9758
Abstract
The generation and reaction of a lactone-derived oxiranyl anion is described. The aldol-type reaction of the epoxylactone and aldehydes was accomplished by a two-step procedure via the trimethylsilyl epoxylactone. The application of this methodology to the total synthesis of (+)-epolactaene and its analogs is described.
Keywords
epolactaene , epoxylactone , TBAF , Aldol reaction
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084523
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