Title of article
Rhodium catalysed coupling reaction of myrcene with ethyl acetoacetate in the ionic liquid 1-ethyl-3-methylimidazolium triflimide
Author/Authors
Kasi Dhanalakshmi، نويسنده , , Michel Vaultier، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
9907
To page
9911
Abstract
The ionic liquid 1-ethyl-3-methylimidazolium triflimide was used successfully as the reaction medium to carry out the rhodium catalysed coupling of myrcene with the active methylene compound ethyl acetoacetate in the presence of TPPMS as the ligand. Coupling product was obtained in 93% isolated yield without any side product formation when a 1:50 ratio of rhodium catalyst/TPPMS was used.
Keywords
sulfoxides , asymmetric reaction , Palladium catalyst , sulfinylzincation
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084537
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