Title of article
Total synthesis of (+)-epiepoformin and (−)-phyllostine
Author/Authors
Hiroaki Okamura، نويسنده , , Hideki Shimizu، نويسنده , , Naomi Yamashita، نويسنده , , Tetsuo Iwagawa، نويسنده , , Munehiro Nakatani، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
6
From page
10159
To page
10164
Abstract
An efficient asymmetric total synthesis of naturally occurring cyclohexeneoxides, (+)-epiepoformin and (−)-phyllostine has been achieved using the chiral building block available from the base-catalyzed Diels–Alder reaction of 3-hydroxy-2-pyrone. Since (−)-theobroxide was derived from the same precursor of (+)-epiepoformin, the formal total synthesis of (−)-theobroxide has also been achieved.
Keywords
theobroxide , Diels–Alder reaction , epiepoformin , Total synthesis , phyllostine
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084564
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