Title of article
Stereochemistry of the [2+4] cycloaddition of cyclopentyne
Author/Authors
John C. Gilbert and Stephen F. Martin، نويسنده , , Duen-Ren Hou، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
6
From page
469
To page
474
Abstract
The [2+4] cycloaddition of cyclopentyne with a pair of diastereomeric 1,3-dienes is found to occur with high stereoselectivity. The results support the applicability of the principles of orbital symmetry even in the case of this exceedingly reactive dienophile.
Keywords
Diels–Alder reaction , Stereochemistry , Orbital symmetry , Cyclopentyne
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1084677
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