Title of article :
Synthesis of cyclopropanes via iodine–magnesium exchange between 3-iodomethyl-1-oxacyclopentanes and organomagnesium reagents
Author/Authors :
Takashi Tsuji، نويسنده , , Tomoaki Nakamura، نويسنده , , Hideki Yorimitsu، نويسنده , , Hiroshi Shinokubo، نويسنده , , Koichiro Oshima، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Iodine–magnesium exchange occurs upon treatment of 3-iodomethyl-1-oxacyclopentanes with alkyl Grignard reagents or trialkylmagnesate. The resulting organomagnesium compounds undergo intramolecular nucleophilic substitution in ether to afford cyclopropane skeletons in a stereoselective manner.
Keywords :
Iodine–magnesium exchange , Cyclopropanes , Ate complex
Journal title :
Tetrahedron
Journal title :
Tetrahedron
