Title of article
Synthesis of cyclopropanes via iodine–magnesium exchange between 3-iodomethyl-1-oxacyclopentanes and organomagnesium reagents
Author/Authors
Takashi Tsuji، نويسنده , , Tomoaki Nakamura، نويسنده , , Hideki Yorimitsu، نويسنده , , Hiroshi Shinokubo، نويسنده , , Koichiro Oshima، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
6
From page
973
To page
978
Abstract
Iodine–magnesium exchange occurs upon treatment of 3-iodomethyl-1-oxacyclopentanes with alkyl Grignard reagents or trialkylmagnesate. The resulting organomagnesium compounds undergo intramolecular nucleophilic substitution in ether to afford cyclopropane skeletons in a stereoselective manner.
Keywords
Iodine–magnesium exchange , Cyclopropanes , Ate complex
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1084787
Link To Document