Title of article
Tandem reactions catalyzed by lanthanide iodides. Part 2: Tandem iminoaldol–enolisation reactions
Author/Authors
Richard Gil، نويسنده , , Marion Eternot، نويسنده , , Marie-George Guillerez، نويسنده , , Jacqueline Collin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
6
From page
3085
To page
3090
Abstract
Samarium diiodide is a catalyst for the reaction of cyclic and acyclic tert-butyldimethylsilyl enoxysilanes with chelating imines. Reaction products are isolated as β-aminoenoxysilanes instead of β-aminoketones as previously observed with the corresponding trimethylsilyl enoxysilanes. Several mechanistic pathways are discussed.
Keywords
Samarium diiodide , Catalysis , Mannich reaction , Imines , Tandem reaction
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085216
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