Title of article
Biotransformation of (+)-(1R,2S)-fenchol by the larvae of common cutworm (Spodoptera litura)
Author/Authors
Mitsuo Miyazawa، نويسنده , , Yohei Miyamoto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
6
From page
3091
To page
3096
Abstract
Biotransformation of (+)-(1R,2S)-fenchol by the larvae of Spodoptera litura was carried out. Substrate was converted to three new terpenoids, (+)-(1R,2S)-10-hydroxyfenchol, (+)-(1R,2R,3S)-8-hydroxyfenchol and (−)-(1S,2S,6S)-6-exo-hydroxyfenchol, and one known terpenoid, (−)-(1R,2R,3R)-9-hydroxyfenchol. These structures were established by NMR, IR, specific rotation and mass spectral studies.
Keywords
(?)-(1S , 6S)-6-exo-Hydroxyfenchol , 2S , 2R , 3R)-9-Hydroxyfenchol , Spodoptera litura , Biotransformation , Hydroxylation , Regioselective , (+)-(1R , 2S)-10-Hydroxyfenchol , 3S)-8-Hydroxyfenchol , 2R , (+)-(1R , (?)-(1R
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085217
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