Title of article
Development of a new class of (1S,3R,4R)-2-azabicyclo[2.2.1]heptane-oxazoline ligands and their application in asymmetric transfer hydrogenation
Author/Authors
Anna Trifonova، نويسنده , , Klas E K?llstr?m، نويسنده , , Pher G Andersson، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
11
From page
3393
To page
3403
Abstract
New 2-aza-norbornane-oxazoline compounds were synthesized and evaluated as ligands in the transfer hydrogenation of acetophenone. The best catalyst prepared in situ from [IrCl2(COD)]2 and a ligand afforded 1-(S)-phenylethanol in good yields and 79% ee.
Keywords
Oxazoline , chiral ligands , (2 , Acetophenone , Catalysis , Asymmetric transfer hydrogenation
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085262
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