• Title of article

    Synthesis of 1,4,5,16-tetrahydroxytetraphenylene

  • Author/Authors

    Chi Wai Hui، نويسنده , , Thomas C.W Mak، نويسنده , , Henry N.C. Wong، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2004
  • Pages
    9
  • From page
    3523
  • To page
    3531
  • Abstract
    This paper concerns the synthesis of 1,4,5,16-tetrahydroxytetraphenylene, which may function as a building block for the construction of molecular scaffolds. The synthesis of 1,4,5,16-tetrahydroxytetraphenylene was realized by stepwise Diels–Alder reactions to form two benzene rings using 1,10-dimethoxydibenzo[a,e]cyclooctene as a precursor. This key intermediate, in turn, could be obtained by photo-rearrangement of its corresponding barrelene.
  • Keywords
    Tetraphenylene , Photo-rearrangement , Diels–Alder reaction , Strained acetylene
  • Journal title
    Tetrahedron
  • Serial Year
    2004
  • Journal title
    Tetrahedron
  • Record number

    1085310