Title of article
Synthesis of 1,4,5,16-tetrahydroxytetraphenylene
Author/Authors
Chi Wai Hui، نويسنده , , Thomas C.W Mak، نويسنده , , Henry N.C. Wong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
9
From page
3523
To page
3531
Abstract
This paper concerns the synthesis of 1,4,5,16-tetrahydroxytetraphenylene, which may function as a building block for the construction of molecular scaffolds. The synthesis of 1,4,5,16-tetrahydroxytetraphenylene was realized by stepwise Diels–Alder reactions to form two benzene rings using 1,10-dimethoxydibenzo[a,e]cyclooctene as a precursor. This key intermediate, in turn, could be obtained by photo-rearrangement of its corresponding barrelene.
Keywords
Tetraphenylene , Photo-rearrangement , Diels–Alder reaction , Strained acetylene
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085310
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