Title of article
17-Diazo pristinamycin IIB preparation and synthetic applications
Author/Authors
Baptiste Ronan، نويسنده , , Eric Bacqué، نويسنده , , Jean-Claude Barrière، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
6
From page
3819
To page
3824
Abstract
We report hereafter the preparation of 17-diazo pristinamycin IIB and its synthetic applications based on the generation of the corresponding carbene/carbenoid. In particular, we describe rhodium-catalyzed insertion reactions and the Wolff rearrangement of this α-diazo-ketone.
Keywords
lactone , diol , Antibiotics , pristinamycins II , ?-Diazo-ketone , Carbene , Wolff rearrangement , rhodium acetate , Ring contraction , Dihydro-furan-3-one , Insertion
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085380
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