Title of article :
17-Diazo pristinamycin IIB preparation and synthetic applications
Author/Authors :
Baptiste Ronan، نويسنده , , Eric Bacqué، نويسنده , , Jean-Claude Barrière، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
We report hereafter the preparation of 17-diazo pristinamycin IIB and its synthetic applications based on the generation of the corresponding carbene/carbenoid. In particular, we describe rhodium-catalyzed insertion reactions and the Wolff rearrangement of this α-diazo-ketone.
Keywords :
lactone , diol , Antibiotics , pristinamycins II , ?-Diazo-ketone , Carbene , Wolff rearrangement , rhodium acetate , Ring contraction , Dihydro-furan-3-one , Insertion
Journal title :
Tetrahedron
Journal title :
Tetrahedron
