Title of article
Towards the synthesis of perfluoroalkylated derivatives of Xantphos
Author/Authors
Dave J. Adams، نويسنده , , David J. Cole-Hamilton، نويسنده , , Duncan A.J. Harding، نويسنده , , Eric G. Hope، نويسنده , , Peter Pogorzelec، نويسنده , , Alison M. Stuart، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
7
From page
4079
To page
4085
Abstract
An analogue of Xantphos incorporating four perfluoroalkyl groups has been prepared and successfully used as a ligand in the rhodium-catalysed hydroformylation of 1-octene in toluene. A number of perfluoroalkylated xanthene backbones have also been synthesised, but their conversion into preferentially perfluorocarbon solvent soluble Xantphos-type ligands, suitable for catalysis in fluorocarbon solvents, has not been successful.
Keywords
Fluorine , phosphines , hydroformylation , Homogeneous catalysis , fluorinated ligands
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085445
Link To Document