gE Model for Single- and Mixed-Solvent Electrolyte Systems. 3. Prediction of Salt Solubilities in Aqueous Electrolyte Systems

The LIQUAC and LIFAC models have been widely used to predict osmotic coefficients, mean ion activity coefficients, the vapor-liquid equilibrium behavior, and the solubility of gases in single- and mixed-solvent electrolyte systems. In this paper, starting from the solubility product calculated using standard thermodynamic properties, the LIQUAC model is used to predict the solubilities of salts consisting of various cations (Na+, K+, and NH4+) and anions (F-, Cl-, Br-, I-, and SO42-) and their mixtures in aqueous solutions as a function of temperature.