Title of article :
Oxidative nucleophilic substitution of hydrogen in nitroarenes with trifluoromethyl carbanions. Synthesis of trifluoromethyl phenols
Author/Authors :
Marek Surowiec، نويسنده , , Mieczys?aw M?kosza، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Trifluoromethyl carbanions generated from the Ruppert reagent and TASF add to highly electron-deficient nitroarenes to produce σH adducts subsequently oxidized with dimethyldioxirane to substituted trifluoromethyl phenols.
Keywords :
Phenols , Dimethyldioxirane , carbanions , nitroarenes , Ruppert reagent
Journal title :
Tetrahedron
Journal title :
Tetrahedron