Author/Authors :
Ping Liu، نويسنده , , Yamin Zhang، نويسنده , , Guiju Feng، نويسنده , , Jianhua Hu، نويسنده , , XIAOPING ZHOU، نويسنده , , Qizhong Zhao، نويسنده , , Yunhua Xu، نويسنده , , Zhen Tong، نويسنده , , Wenji Deng، نويسنده ,
Abstract :
In order to develop novel oligothiophene-based liquid crystals capable of hydrogen bonding, new terthiophene derivatives containing an alkylamide group, N,N′-dialkyl-5,5″-dichloro-2,2′:5′,2″-terthiophene-4,4″-dicarboxamide (DNCnDCl3T, n=8, 18), N,N′-dialkyl-5,5″-dibromo-2,2′:5′,2″-terthiophene-4,4″-dicarboxamide (DNCnDBr3T, n=5, 8, 16, 18), or N,N′-dialkyl-5,5″-diiodo-2,2′:5′,2″-terthiophene-4,4″-dica-rboxamide (DNCnDI3T, n=8, 18), were designed and synthesized, and their thermal behaviour was examined. It was found that DNC18DCl3T, DNC18DI3T and DNCnDBr3T (n=8, 16, 18) form a smectic A phase and that the alkyl chain length greatly affects liquid crystal phase formation. The absence of liquid crystallinity in the corresponding ester derivatives suggests that intermolecular hydrogen bonding also plays a role in the formation of a liquid crystal phases in the DNCnDBr3T system.
