Title of article :
(PCy3)2Cl2RuCHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation
Author/Authors :
Belinda T. Lee، نويسنده , , Thomas O. Schrader، نويسنده , , Belén Mart??n-Matute، نويسنده , , Christopher R. Kauffman، نويسنده , , Peng Zhang، نويسنده , , Marc L. Snapper، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
(PCy3)2Cl2RuCHPh-catalyzed Kharasch additions of trihaloalkanes across olefins provide polyhalogenated adducts, which upon hydrolysis furnish α,β-unsaturated ketones, aldehydes, or γ-hydroxybutenolides. This two-step process represents an overall acylation or carbonylation of an olefin.
Keywords :
Kharasch , Metathesis , Radical , Carbonylation
Journal title :
Tetrahedron
Journal title :
Tetrahedron