• Title of article

    (PCy3)2Cl2RuCHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation

  • Author/Authors

    Belinda T. Lee، نويسنده , , Thomas O. Schrader، نويسنده , , Belén Mart??n-Matute، نويسنده , , Christopher R. Kauffman، نويسنده , , Peng Zhang، نويسنده , , Marc L. Snapper، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2004
  • Pages
    6
  • From page
    7391
  • To page
    7396
  • Abstract
    (PCy3)2Cl2RuCHPh-catalyzed Kharasch additions of trihaloalkanes across olefins provide polyhalogenated adducts, which upon hydrolysis furnish α,β-unsaturated ketones, aldehydes, or γ-hydroxybutenolides. This two-step process represents an overall acylation or carbonylation of an olefin.
  • Keywords
    Kharasch , Metathesis , Radical , Carbonylation
  • Journal title
    Tetrahedron
  • Serial Year
    2004
  • Journal title
    Tetrahedron
  • Record number

    1086967