Title of article
Sequenced elimination–reduction and elimination–cyclopropanation reactions of 2,3-epoxyamides promoted by samarium diiodide. Synthesis of 2,3-dideuterioamides and cyclopropanamides
Author/Authors
José M. Concell?n، نويسنده , , M?nica Huerta، نويسنده , , Eva Bardales، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
7
From page
10059
To page
10065
Abstract
An easy and general sequenced elimination/reduction or elimination/cyclopropanation process promoted by samarium diiodide or/and CH2I2/Sm provide an efficient method for synthesising 2,3-dideuterioamides or cyclopropanamides , respectively. The transformations take place in high yields and with total or high selectivity from the easily available 2,3-epoxyamides.
Keywords
Samarium diiodide , Sequenced reactions , deuterium , Saturated amides , Cyclopropanamides
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1087215
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