Title of article
Synthetic studies towards the novel fomannosane sesquiterpenoid illudosin: framework construction
Author/Authors
Goverdhan Mehta، نويسنده , , K Sreenivas، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
6
From page
3475
To page
3480
Abstract
A synthetic approach to the novel fomannosane sesquiterpene natural product illudosin from the diquinane precursor , readily available in turn from commercial 1,5-cyclooctadiene, is delineated. The key steps are the stereoselective construction of the cis, anti, cis-tricyclo[6.2.0.02,6]decane system, strategic C–C bond disengagement through Baeyer–Villiger oxidation and functional group adjustments to deliver the carbocyclic core present in the natural product.
Keywords
cyclobutanoids , photocycloaddition , enone transposition , Baeyer–Villiger oxidation , farnesyl pyrophosphate
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087764
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