Title of article
Remarkable reactivity of pyridinium chlorochromate adsorbed on neutral alumina under solvent-free conditions
Author/Authors
Sanjay Bhar، نويسنده , , Subrata Kumar Chaudhuri، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
6
From page
3493
To page
3498
Abstract
Pyridinium chlorochromate adsorbed on neutral alumina (PCC-Al2O3) under solvent-free conditions has been found to oxidize primary aliphatic alcohols to alkyl alkanoates whereas primary benzylic and primary allylic alcohols produce the corresponding aldehydes. Secondary aliphatic and aromatic alcohols produce ketones without isomerization and polymerization of double bonds, overoxidation and other side-reactions.
Keywords
Solid-phase synthesis , supported reagents , Oxidation
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087767
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