Title of article
‘Locking’ dendrimer conformation through metal coordination
Author/Authors
Mark R. Rauckhorst، نويسنده , , Paul J Wilson، نويسنده , , Susan A Hatcher، نويسنده , , Christopher M Hadad، نويسنده , , Jon R. Parquette، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
7
From page
3917
To page
3923
Abstract
Chiral intramolecularly hydrogen-bonded dendrons that fold into a dynamically biased helical conformation can be ‘locked’ in kinetically controlled conformations by coordination to copper(II) metal centers. Covalent bonding of each pyridine-2,6-dicarboxamide repeat unit of the dendrons to a copper metal center forces this subunit to exist in only the syn–syn conformation and dramatically rigidifies the dendron structure.
Keywords
dendrimer conformation , copper(II) metal centers , syn–syn conformation
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087812
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